Review on kinetic studies of α-hydroxy acids (glycolic, mandelic, citric, tartaric and malic) and some other organic compounds with water soluble nano particles of colloidal MnO2 in absence and presence of non-ionic surfactant (TX-100)

Author:

Iqubal S. M. ShakeelORCID

Abstract

AbstractThis review paper deals with the kinetic studies of α-hydroxy acids (glycolic, mandelic, citric, tartaric, and malic) and some other organic compounds with water soluble nano particles of colloidal MnO2 in the aqueous and micellar media i.e., non- ionic surfactant (TX-100). The reaction has both non-autocatalytic and autocatalytic paths. Both in the absence and presence of non-ionic surfactant i.e., Triton X-100, first-order rate with respect to colloidal MnO2 and α-hydroxy acids is observed. Non-ionic surfactant (Triton X-100) catalyses the reaction due to multiple hydrogen bonding (intermolecular hydrogen bonding) whereas cationic CTAB (cetyl trimethyl ammonium bromide) and SDS (sodium dodecyl sulphate) show no effect.

Publisher

Springer Science and Business Media LLC

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