Two-Phase Flow in Porous Electrodes of Proton Exchange Membrane Fuel Cell

Abstract

AbstractWater management in porous electrodes bears significance due to its strong potential in determining the performance of proton exchange membrane fuel cell. In terms of porous electrodes, internal water distribution and removal process have extensively attracted attention in both experimental and numerical studies. However, the structural difference among the catalyst layer (CL), microporous layer (MPL), and gas diffusion layer (GDL) leads to significant challenges in studying the two-phase flow behavior. Given the different porosities and pore scales of the CL, MPL, and GDL, the model scales in simulating each component are inconsistent. This review emphasizes the numerical simulation related to porous electrodes in the water transport process and evaluates the effectiveness and weakness of the conventional methods used during the investigation. The limitations of existing models include the following: (i) The reconstruction of geometric models is difficult to achieve when using the real characteristics of the components; (ii) the computational domain size is limited due to massive computational loads in three-dimensional (3D) simulations; (iii) numerical associations among 3D models are lacking because of the separate studies for each component; (iv) the effects of vapor condensation and heat transfer on the two-phase flow are disregarded; (v) compressive deformation during assembly and vibration in road conditions should be considered in two-phase flow studies given the real operating conditions. Therefore, this review is aimed at critical research gaps which need further investigation. Insightful potential research directions are also suggested for future improvements.