A Fundamental Equation of State for Chloroethene for Temperatures from the Triple Point to 430 K and Pressures to 100 MPa-Reference-Cited by-同舟云学术

A Fundamental Equation of State for Chloroethene for Temperatures from the Triple Point to 430 K and Pressures to 100 MPa

Published:2022-01-10 Issue:3 Volume:43 Page:
ISSN:0195-928X
Container-title:International Journal of Thermophysics
language:en
Short-container-title:Int J Thermophys

Author:

Thol Monika^ORCID,Fenkl Florian,Lemmon Eric W.

Abstract

AbstractA fundamental equation of state in terms of the Helmholtz energy is presented for chloroethene (vinyl chloride). Due to its fundamental nature, it can be used to consistently calculate all thermodynamic state properties in the fluid region. Based on the underlying experimental database, it is valid from the triple-point temperature 119.31 K to 430 K with a maximum pressure of 100 MPa. In addition to the accurate reproduction of experimental data, correct extrapolation behavior during the development of the equation was attained. This enables the equation to be applied in modern mixture frameworks.

Funder

Ruhr-Universität Bochum

Publisher

Springer Science and Business Media LLC

Subject

Condensed Matter Physics

Link

https://link.springer.com/content/pdf/10.1007/s10765-021-02961-3.pdf

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