Author:
Hall Rebecca L.,de Santana Felipe Bachion,Grunsky Eric C.,Browne Margaret A.,Lowe Victoria,Fitzsimons Mairéad,Higgins Suzanne,Gallagher Vincent,Daly Karen
Abstract
Abstract
Purpose
Mehlich-3 extractable P, Al, Ca, and Fe combined with pH can be used to help explain soil chemical processes which regulate P retention, such as the role of Al, Ca, Fe, and pH levels in P fixation and buffering capacity. However, Mehlich-3 is not always the standard test used in agriculture. The objective of this study is to assess the most reliable conversion of Mehlich-3 Al, Ca, Fe, and P and pH into a commonly used soil P test, Morgan’s P, and specifically to predict values into decision support for fertiliser recommendations.
Methods
A geochemical database of 5631 mineral soil samples which covered the northern area of Ireland was used to model soil test P and P indices using Mehlich-3 data.
Results
A random forest machine learning algorithm produced an R2 of 0.96 and accurately predicted soil P index from external validation in 90% of samples (with an error range of ± 1 mg L−1). The model accuracy was reduced when predicted Morgan’s P concentration was outside of the sampled area.
Conclusions
It is recommended that random forest is used to produce Mehlich-3 conversions, especially when data covers large spatial scales with large heterogeneity in soil types and regional variations. To implement conversion models into P testing regimes, it is recommended that representative soil types/geochemical attributes are present in the dataset. Furthermore, completion of a national scale geochemical survey is needed. This will enable accurate predictions of Morgan’s P concentration for a wider range of soils and geographical scale.
Funder
Geological Survey of Ireland
Publisher
Springer Science and Business Media LLC
Subject
Stratigraphy,Earth-Surface Processes
Reference37 articles.
1. Aitchison J (1986) The statistical analysis of compositional data. Chapman and Hall, New York, 416p
2. Bhatta A, Prasad R, Chakraborty D, Shaw JN, Lamba J, Brantley E, Torbert HA (2021) Mehlich 3 as a generic soil test extractant for environmental phosphorus risk assessment across Alabama soil regions. Agrosyst Geosci Environ 4(3). https://doi.org/10.1002/agg2.20187
3. Chen J, Cordero I, Moorhead DL, Rowntree JK, Simpson LT, Bardgett RD, Craig H (2023) Trade-off between microbial carbon use efficiency and specific nutrient-acquiring extracellular enzyme activities under reduced oxygen. Soil Ecol Lett 5(2). https://doi.org/10.1007/s42832-022-0157-z
4. Corine (2019) Corine Land Cover 2018 (vector) - version 20, Jun. 2019. Online. Available at: https://sdi.eea.europa.eu/catalogue/srv/api/records/53ef1493-e7a1-4216-b043-87a7c2a5a68d. Accessed 11 Sept 2023
5. Cui Y, Moorhead DL, Wang X, Xu M, Wang X, Wei X, Zhu Z, Ge T, Peng S, Zhu B, Zhang X, Fang L (2022) Decreasing microbial phosphorus limitation increases soil carbon release. Geoderma 419(February):115868. https://doi.org/10.1016/j.geoderma.2022.115868