The application of chromatographic methods in optimization and the enhancement of the oxidative liquefaction process to wind turbine blade recycling

Abstract

AbstractThe concept of the circular economy aims to maximise the longevity of raw materials, materials, and final goods while simultaneously minimising waste generation. In order to accomplish this objective, researchers are currently exploring emission-free recycling methods and advancing a novel oxidative liquefaction methodology. This process is employed to efficiently degrade the polymer matrix which we can find among other things in wind turbine blades while also conducting chromatographic investigations of the resulting degraded resins. The conducted experiments included a temperature range spanning from 250 °C to 350 °C. The residence lengths varied from 30 to 90 min, while the pressures ranged from 20 to 40 bars. Additionally, the waste-to-liquid ratios were within the range of 5–25%, and the oxidant concentrations were between 15 and 45% by weight. The study’s results will help improve the design of the experiments by focusing on getting the highest concentrations of oxygenated chemical compounds, such as volatile fatty acids, aromatic hydrocarbons, and aromatic carboxylic acids. These compounds are the main chemicals obtained during resin degradation, and identifying the optimal conditions for their production will facilitate the implementation of this process on a larger scale. Graphic abstract