Abstract
AbstractReduction reactions of unsaturated compounds are fundamental transformations in synthetic chemistry. In this context, the reduction of polarized double bonds such as carbonyl or C=C motifs can be achieved by hydrogenation reactions. We describe here a highly chemoselective Mn(I)-based PNP pincer catalyst for the hydrosilylation of aldehydes and ketones employing polymethylhydrosiloxane (PMHS) as inexpensive hydrogen donor.
Graphic abstract
Funder
Österreichische Forschungsförderungsgesellschaft
TU Wien
Publisher
Springer Science and Business Media LLC
Cited by
2 articles.
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