New halimane and clerodane diterpenoids from Croton cnidophyllus

Author:

Wei Xun,Huang Jia-Luo,Gao Hua-Hua,Yuan Fang-Yu,Tang Gui-HuaORCID,Yin Sheng

Abstract

AbstractThree new halimane furanoditerpenoids (13) and three new clerodane furanoditerpenoids (46), along with seven known terpenoids including four pimarane diterpenoids (710) and three norisoprenoids (1113) were isolated from the 95% EtOH extracts of the plants of Croton cnidophyllus. The 2D structures including absolute configuration of new furanoditerpenoids (16) were elucidated by analysis of their HRMS and NMR data as well as comparison of experimental and calculated ECD curves. Bioassay revealed that two compounds (8 and 9) possessed certain inhibitory effects against NO production stimulated by LPS, with IC50 values of 19.00 ± 1.76 and 21.61 ± 1.11 μM, respectively. Graphical Abstract

Funder

National Natural Science Foundation of China

Science and Technology Program of Guangzhou, China

Southern Marine Science and Engineering Guangdong Laboratory

Open Program of Shenzhen Bay Laboratory

Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program

Guangdong Basic and Applied Basic Research Foundation, China

Publisher

Springer Science and Business Media LLC

Subject

Organic Chemistry,Plant Science,Pharmacology,Toxicology,Biochemistry,Food Science,Analytical Chemistry

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