Abstract
AbstractWe have measured depletion spectra of the heteronuclear (85Rb87Rb+) dimer cation complexed with up to 10 He atoms. Two absorption bands are observed between 920 and 250 nm. The transition into the repulsive 12Σu+state of HeRb2+gives rise to a broad feature at 790 nm (12,650 cm−1); it exhibits a blueshift of 98 cm−1per added He atom. The transition into the bound 12Πustate of HeRb2+reveals vibrational structure with a band head at ≤ 15,522 cm−1, a harmonic constant of 26 cm−1, and a spin–orbit splitting of ≤ 183 cm−1. The band experiences an average redshift of − 38 cm−1per added He atom. Ab initio calculations rationalize the shape of the spectra and spectral shifts with respect to the number of helium atoms attached. For a higher number of solvating helium atoms, symmetric solvation on both ends of the Rb2+ion is predicted.
Funder
European Regional Development Fund
Österreichische Forschungsförderungsgesellschaft
Horizon 2020
University of Innsbruck and Medical University of Innsbruck
Publisher
Springer Science and Business Media LLC
Subject
Physical and Theoretical Chemistry
Cited by
5 articles.
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