Author:
Johnson David A.,Nelson Peter G.
Abstract
Abstract
The valencies of the lanthanides vary more than was once thought. In addition to valencies associated with a half-full shell, there are valencies associated with a quarter- and three-quarter-full shell. This can be explained on the basis of Slater’s theory of many-electron atoms. The same theory explains the variation in complexing constants in the trivalent state (the “tetrad effect”). Valency in metallic and organometallic compounds is also discussed.
Publisher
Springer Science and Business Media LLC
Subject
History,Biochemistry,General Chemistry
Cited by
8 articles.
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