Interactions of polyvinyl acetate dispersions with nanostructured superhydrophilic and superhydrophobic Ti6Al4V alloy surfaces-Reference-Cited by-同舟云学术

Interactions of polyvinyl acetate dispersions with nanostructured superhydrophilic and superhydrophobic Ti6Al4V alloy surfaces

Published:2024-05-27 Issue:6 Volume:6 Page:
ISSN:3004-9261
Container-title:Discover Applied Sciences
language:en
Short-container-title:Discov Appl Sci

Author:

Neßlinger Vanessa,Atlanov Jan,Grundmeier Guido

Abstract

AbstractNanostructured bilayer thin films with superhydrophobic and superhydrophilic surfaces were prepared using Ti6Al4V alloy substrates which allowed for the comparative analysis of polyvinyl acetate (PVAc) particle adsorption as a function of the interface structure. The PVAc particles were obtained from emulsion polymerization of vinyl acetate. A superhydrophilic TiO2 nanofiber-based 3D network was created on the Ti6Al4V alloy substrate by application of a hydrothermal method. Subsequent UV-grafting of ultra-thin polydimethylsiloxane (PDMS) layers resulted in a superhydrophobic surface. The modification steps were followed via Diffuse Reflectance Infrared Fourier Transform Spectroscopy, X-ray Photoelectron Spectroscopy, Field Emission-Scanning Electron Microscopy, contact angle and Electrochemical Impedance Spectroscopy. A mechanism for the adsorption of PVAc at the two electrolyte/substrate interfaces could be revealed.

Funder

German Federal Ministry for Economic Affairs and Climate Action

Universität Paderborn

Publisher

Springer Science and Business Media LLC

Link

https://link.springer.com/content/pdf/10.1007/s42452-024-05916-z.pdf

Reference70 articles.

1. Rust S, Pauer W. Formulation and process determined fouling prediction for the continuous emulsion co polymerisation of vinyl acetate. J Polym Res. 2023;30(6):242. https://doi.org/10.1007/s10965-023-03588-8.

2. Neßlinger V, Orive AG, Meinderink D, Grundmeier G. Combined in-situ attenuated total reflection-fourier transform infrared spectroscopy and single molecule force studies of poly(acrylic acid) at electrolyte/oxide interfaces at acidic pH. J Colloid Interface Sci. 2022;615:563–76. https://doi.org/10.1016/j.jcis.2022.01.175.

3. Srebnik S. Polymer adsorption on multicomponent surfaces with relevance to membrane fouling. Chem Eng Sci. 2003;58(23–24):5291–8. https://doi.org/10.1016/j.ces.2003.05.008.

4. Horseman T, Wang Z, Lin S. Colloidal interactions between model foulants and engineered surfaces: interplay between roughness and surface energy. Chem Eng J Adv. 2021;8:100138. https://doi.org/10.1016/j.ceja.2021.100138.

5. Hohlen A, Augustin W, Scholl S. Quantification of polymer fouling on heat transfer surfaces during synthesis. Macro React Eng. 2020;14(1):1900035. https://doi.org/10.1002/mren.201900035.