Homogeneous Reactions
Reference25 articles.
1. The method of determining the rank of the stoichiometric matrix presents some subtlety when different isomers may be present in the reacting mixture; see J. C. Whitwell and R. S. Dartt, AIChE J.
19, 1114 (1973).
2. Proof that the reaction subspace and the composition space coincide only in the case of isomerization and polymerization reactions is given by G. Astarita, Chem. Eng. Sci.
31, 1224 (1976).
3. Direct coupling between different chemical reactions is generally excluded as a possibility in the chemical literature; the point is discussed by M. J. Boudart, J. Phys. Chem.
87, 2286 (1983).
4. The implications of the strong constraint, that every individual chemical reaction proceeds with a nonnegative dissipation rate on possible reaction pathways, are discussed by R. Shinnar and C. A. Feng, Ind. Eng. Chem., Fundam.
24, 153 (1985).
5. There is ample literature on the mathematics of stoichiometry and mass action kinetics; two important references are E. H. Kerner, Bull. Math. Biophys.
34, 243 (1972).