On the evolution and application of the concept of electrochemical polarization

Abstract

AbstractThis paper yields an overview on the evolution of the concept of polarization applied to electrochemical systems, ranging from electrodes to cells. The historical discussion starts at the early phase of the development of electrochemistry when current-controlled measurements were possible only, and when the early definitions of polarization, depolarization and depolarizer were created. A number of contemporary handbooks, recommendations and other reference resources are listed in which these concepts are represented in various ways, from conservative definitions to attempts of redefining them. The traditional definitions are confronted with the everyday use of professional language, drawing attention to the fact that the widespread application of potential-controlled electrochemical measurements led to new meanings. Some suggestions are made that open room for the application of the term of polarization in accord with the modern methodologies, without compromising the traditional introduction of the term. Polarization-related phenomena in biological membranes are not dealt with in the present work.