Abstract
AbstractMetals often are classified as “noble” or “base”—characterizing their reduction potential as one of the most important chemical properties. We show that metals are only as noble as allowed by their environment, i.e. this is a relative term, and the “frame of reference” simply is the solvent in which the redox system is present. We prove that silver is a prime example for a noble metal that forfeits its noble character in the simple ionic liquid HMIM Br (1-hexyl-3-methylimidazolium bromide) as an example for such a solvent.
Funder
European Metrology Programme for Innovation and Research
DFG
Publisher
Springer Science and Business Media LLC
Subject
Electrical and Electronic Engineering,Electrochemistry,Condensed Matter Physics,General Materials Science
Cited by
1 articles.
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