Hydrophysical properties of sandy clay contaminated by petroleum hydrocarbon

Abstract

AbstractThe aim of the presented research was to assess the changes in hydro-physical properties of sandy clay under the influence of petroleum hydrocarbon contamination. An understanding of these changes is fundamental in the right remedial actions and for further use of soil. Laboratory tests of inherently wettable sandy clay showed that the petroleum hydrocarbon induced potential soil water repellency (SWR) of extremely repellent class at the contamination of 18 g kg−1. The relationship between soil water potential (pF) and SWR determined by the WDPT test for given hydrocarbon contamination, i.e., 6, 12, 18, 30, 100 g kg−1, showed that the critical soil moisture value (CSMC) corresponds to the pF = 1.0 ÷ 1.5. Soil retention characteristic (pF) showed that an increase in hydrocarbon contamination from 0 to 100 g kg−1 caused a reduction of total available water for plants from about 0.19 to 0.06 cm cm−3. At the same time, in the pF = 1.5 ÷ 2.0 range, intensive soil pore drainage was observed. Statistically, significant effect of hydrocarbon contamination and soil moisture potential on SWR was found. Soil hydrophobicity limits the addition of soil retention, because a significant part of the precipitation can be transformed by surface runoff. The carried out tests showed that at a hydrocarbon contamination of 30 g kg−1, total rainfall amount 14 mm with an intensity of 2 mm h−1 was transformed into a surface drain in approx. 40%. The conducted studies demonstrate the adverse impact of hydrocarbon contamination on the soil’s hydro-physical properties. The soil water retention reduction and launching of the surface outflow, as a result of limiting the water penetration process resulting from SWR, change the agrohydrological conditions of the contaminated area. It can result as the imbalance of the flow of energy and matter in the ecosystem. The scenarios of environmental effects, among others, depend on the type of soil, the degree of its pollution, the type of ecosystem, and supporting activities undertaken by man. It should be taken into account that the increasing frequency of drought occurrence associated with climate change is conducive to the phenomenon of SWR regardless of the reasons for its occurrence.