Potentials of mono- and multi-metal ion removal from water with cotton stalks and date palm stone residuals

Abstract

AbstractIn this work, cotton stalks (Gossypium barbadense) and date palm stones (Phoenix dactylifera) have been used as biosorbents to remove cadmium; Cd(II), lead; Pb(II), and zinc; Zn(II) from mono- and multi-solutions. Each biosorbent was characterized using SEM-EDX, and FT-IR. The findings showed that pH, dose, contact time, metal concentration, and particle size affect the treatment process. The adsorption pattern was Pb(II) > Cd(II) > Zn(II) for both biosorbents. The adsorption performance of cotton stalks was higher than that of date palm stones. The fitted maximum uptake capacities; qm of cotton stalks were higher than those of date palm stones. The maximum adsorption at optimum conditions of Pb(II), Cd(II), and Zn(II) with cotton stalks were 98%, 92.1%, and 78.9%, respectively, within 30 min. While the maximum adsorption of Pb(II), Cd(II), and Zn(II) with date palm stones were 94.6%, 76%, and 68.6%, respectively. Results confirmed the antagonistic effect of heavy metal removal at optimum conditions. Biosorbents could remove ~ 100% of the metal ions from real wastewater samples. Regeneration investigation revealed a successful reusability of both biosorbents for four cycles.