Conversion of Chemical into Mechanical Energy by Synsthetic Polymer Gels (Chemomechanical System)
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Springer US
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http://link.springer.com/content/pdf/10.1007/978-1-4684-5892-3_15.pdf
Reference18 articles.
1. Mechanochemical (chemomechanical) system is well known as a model converting chemical into mechanical energy and a variety of systems have been reported. The system developed by us is considered as a prototype model of a chemomechanical (mechanochemica1) system operated under electric similus. We prefer the term “chemomechanical reaction,” “chemomechanical system” instead of “mechanochemical” proposed by A. Katchalsky to give more precise difinition and to avoid a confusion with other terminology. Note that Mechanochemical reaction often refers to chemical reaction induced by mechanical stress fracture and dumpling to give radical and crosslinking formation. Y.Osada, Adv.Polymr Sci., 82, 1(1987)]
2. Transformation from mechanical into chemical energy may be envisaged in which the application of mechanical energy may rise the chemical potential of substance and permit its transfer from a reservoir of a lower chemical potential to a reservoir of higher potential (reverse chemomechanical system). Details are given in Y. Osada, Adv. Polym. Sci., 82, 1, springer-Ver1ag, Heidelberg, 1987.
3. K. Iwasa and T. Tasaki, Biochem. Biophys. Res. Comm., 95, 1328(1980). I. Tasaki, K. Iwasa, Structure and Function of Excitable Gel. ed. by D.C. Chang, I. Tasaki, W.J. Adelman and H. R. Leuchtag Plenum Pub., Corp. New York, 307(1983).
4. Y. Osada, M. Hasebe, Chem. Lett., 1985, 1285.
5. Y. H. Bae, T. Okano, R. Hsu, S.W. Kim, Makromol Chem. Rapid Comm. 8, 481(1987).
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