Abstract
Abstract The purple Cameroon grass crop (P. purpureum cv. Morado) presents significant potential as a source of raw materials and renewable energy; it has rapid growth, high yield, and low fertilizer demand. During the conversion of lignocellulosic biomass, hemicellulose and cellulose can first be hydrolyzed into five and six-carbon sugars, and then the sugars are converted into furfural and levulinic acid (LA) respectively. In this work, the furfural and levunilic acid production was evaluated in a two-stage catalytic process with a tin catalyst supported on a sulfonated activated carbon. In the first stage, a furfural yield of 23.28% at 170 °C for 3 h. In the second stage, the effect of process temperature and time on LA production's yield and energy demand was evaluated; LA yield of 28.17% was obtained with an energy demand of 0.12 kWh/gLA at 180.47 °C for 1.78 h. These results demonstrate the possibility of obtaining furfural from Cameroon grass.
Graphical Abstract
Funder
Universidad de Bogotá Jorge Tadeo Lozano
National University of Colombia
Publisher
Springer Science and Business Media LLC
Subject
Renewable Energy, Sustainability and the Environment
Reference61 articles.
1. Wang K, Ye J, Zhou M, Liu P, Liang X, Jiang J (2017) Selective conversion of cellulose to levulinic acid and furfural in sulfolane/water solvent. Cellulose 24:1383–1394. https://doi.org/10.1007/s10570-016-1184-7
2. New EK, Tnah SK, Voon KS, Yong KJ, Procentese A, Yee Shak KP, Subramonian W, Cheng CK, Wu TY (2022) The application of green solvent in a biorefinery using lignocellulosic biomass as a feedstock. J Environ Manag 307:114385. https://doi.org/10.1016/j.jenvman.2021.114385
3. Fontoura CF, Brandão LE, Gomes LL (2015) Elephant grass biorefineries: towards a cleaner Brazilian energy matrix? J Clean Prod 96:85–93. https://doi.org/10.1016/j.jclepro.2014.02.062
4. Gürbüz EI, Wettstein SG, Dumesic JA (2012) Conversion of hemicellulose to furfural and levulinic acid using biphasic reactors with alkylphenol solvents. Chemsuschem 5(2):383–387. https://doi.org/10.1002/cssc.201100608
5. Cerdas R, Vallejos E (2010) Productivity of Camerun grass (Pennisetum purpureum) under different nitrogen fertilizer doses and harvest frequencies in the dry tropical forest of Costa Rica. InterSedes 11(22-2010):180–195. Available: https://revistas.ucr.ac.cr/index.php/intersedes/article/view/993/1054