Epoxidation of Light Olefin Mixtures with Hydrogen Peroxide on TS-1 Catalyst

Abstract

AbstractThe direct epoxidation of mixed ethene and propene feedstocks using hydrogen peroxide over a titanium silicalite (TS-1) catalyst was investigated within a continuous trickle bed reactor operating in laboratory scale. Methanol was employed as the reaction solvent. This study aimed to streamline the epoxidation process by obviating the need for prior separation of alkenes, thereby enhancing process efficiency. An extensive array of operational parameters was explored in a trickle bed reactor, encompassing experimental parameters such as temperature, total pressure, hydrogen peroxide concentration, liquid flow rate, and gas composition. In contrast to prior investigations involving separate ethene and propene epoxidation, this study revealed a reduction in epoxide selectivity. The principal by-products observed were methoxy species, formed through the interaction between the epoxide and methanol, resulting in a ring-opening reaction. The influence of water on this ring-opening process was negligible. Notably, the tunability of the system was demonstrated, highlighting low temperature and elevated partial ethene pressure as pivotal factors for augmentingthe epoxide selectivity. The findings suggest that binary olefin mixtures exhibit diminished selectivity but improved stability. This behavior is potentially linked to the olefin solubility in methanol, or alterations in the surface species concentrations, typically associated with catalyst activity variations. These insights offer a valuable foundation for understanding and optimizing the direct epoxidation of mixed ethene and propene feedstock. Graphical Abstract