Author:
Fankhänel Beate,Schmid Ekaterina,Stelter Michael
Abstract
AbstractThis chapter presents the most important results of investigations on reactive filter materials for the purification of aluminum melts. Reactive filter materials were developed with the aim to remove impurities dissolved in the melt, such as hydrogen from liquid aluminum, by means of specific chemical interactions between the molten metal and the filter material. Selected ceramic foam filters, consisting of carbon-free and carbon-bonded ceramics, were used in their uncoated state as well as treated with various coatings. Numerous fundamental studies were carried out to evaluate the applicability of the new filter materials: sessile-drop-experiments, immersion and filtration tests, the metallographic evaluation of the used filters and the metal samples retrieved from these experiments. Interfacial reactions and the purity of the treated melts were determined with the help of these experiments, following microstructural analyses to obtain indications for the filtration properties and the potential chemical reactions between the filter material and the melt. As a result, it was possible to determine that spodumene, LiAl(Si2O6), positively influences the hydrogen porosity of aluminum castings when applied as a reactive filter material. Filtration alone already helps to prevent areas of increased macroporosity by calming the melt flow, but filter materials containing spodumene further affect microporosity in the castings in positive ways.
Publisher
Springer International Publishing
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