Preliminary Investigation on the Thermodynamic Evaluation and Phase Evolution of Soda Ash-Assisted Roast Treatment of Alluvial Columbite for Recovery of Niobium and Tantalum

Abstract

AbstractAlkaline roasting of a low-grade alluvial silica-based columbite bearing mineral from the Rayfield–Jos deposits (located in South Jos, Plateau state, Federal Republic of Nigeria) was conducted with specific emphasis on the evaluation of thermodynamic reactions as well as the mineral phase evolution during the extraction of Nb and Ta. An isothermal roasting procedure was investigated in order to understand the effects of different soda ash to sample mass ratios as well as the roasting temperatures on the measure or rate of the recoveries of Nb and Ta complexes. Thus, the feasibility rate of a successful alluvial columbite mineral roasting was determined to be influenced by certain optimal process conditions or optimum values of the study parameters, such as alkali to sample mass ratio and, more essentially, the roasting temperature. Therefore, the thermodynamic feasibility of the alkali-carbothermic roasting procedure was also investigated and the resulting chemical reactions were evaluated using the HSC chemistry 9.0 software. Premised on this, the results obtained as well as the thermodynamic data realized from the study demonstrated the feasibility of successful dissolutions of Nb and Ta into a pregnant leached-liquor stream (PLS), without the use of the conventional harmful, hazardous, toxic, and environmentally unfriendly hydrofluoric (HF) acid.