1. A. D. Pomogailo and V. S. Savost'yanov,Synthesis and Polymerization of Metal-Containing Monomers (CRC Press, Boca Raton, FL, 1994); J. E. Mark, H. R. Alleock, and R. West,Inorganic Polymers (Prentice Hall, New Jersey, 1992);Inorganic and Organometallic Oligomers and Polymers, J. F. Harrod and R. M. Laine, eds. (Kluwer Academic, Dordrecht, 1991);Inorganic and Organometallic Polymers, M. Zeldin, K. J. Wynne, and H. R. Allcock, eds. (American Chemical Society, Washington DC, 1988); E. W. Neuse and H. Rosenberg,Metallocene Polymers (Marcel Dekker, New York, 1970).
2. For example, by the end of 1994 there were over 170 patents applied for and granted to inventions related to the synthesis and use of silsesquioxane polymers. A sampling of patents are S.-I. Fukuyama. Y. Yoneda, M. Miyagawa, and K. Nishii, Eur. Pat. Appl. EP 163 583 A3 (1985) pattern-forming resist material: H. Sugiyama, K. Nate, T. Inoue, and A. Mizushima, U.S. Pat. 4.745.169 (1988) alkali soluble photoresist: B. G. Bagley. C. R. Kurkjian, and W. E. Quinn, U.S. Pat. 4.835.057 (1989) fiber optic coating: T. Morimoto and H. Yoshioka, U.S. Pat. 5,039,771 (1991) efficient preparative method; P. K. Pawar and F. J. Traver, Eur. Pat. Appl. EP 470 442 A2 (1991) a glass coating material; H. G. Linde and R. A. Previti-Kelly, U.S. Pat. 5.043.789 (1991) insulating material: I. Ono and H. Yoshioka, U.S. Pat 5,319,049 (1994) fungicide material; M. F. Sojka, U.S. Pat. 5,356,616 (1994) nail lacquer formulation.
3. Some reviews are I. I. Tverdokhlebova and T. A. Larina,Russ. Chem. Rev. 44, 170 (1975). translated fromUsp. Khim. 44, 367 (1975); A. M. Ton'shin, B. A. Kamaritskii, and V. N. Spektor,Russ. Chem. Rev. 52, 775 (1983), translated fromUsp. Khim. 52, 1365 (1983); V. P. Korchkov and T. N. Martynova,J. Appl. Chem. U.S.S.R. 58, 1923 (1985), translated fromZh. Prikl. Khim. 58, 2089 (1985).
4. J. D. Lichtenhan, N. Q. Vu, J. A. Carter, J. W. Gilman, and F. J. Feher,Macromolecules 26, 2141 (1993); J. D. Lichtenhan, Robert A, Mantz, Paul F. Jones, and Michael J. Carr.Polym. Prepr. 35, 523 (1994); J. D. Lichtenhan,Comm. Inorg. Chem. 17, 115 (1995); J. D. Lichtenhan and T. S. Haddad, work in progress.
5. Some well-defined, metal-containing POSS-clusters have been synthesized from the baseassisted degradation of polyphenylsilsesquioxane followed by metal-sodium exchange to form a small metal oxide framework sandwiched between two (PhSiO1.5)6 units. V. A. Igonin, O. I. Shchegolikhina, S. V. Lindeman, M. M. Levitsky, Yu. T. Struchkov, and A. A. Zhdanov,J. Organomet. Chem. 423, 351 (1992) and references therein.