Synthesis and Characterization of Unsymmetrical Schiff Base and Transitıon Metal Complexes

Author:

ÇAKRAN Halide Sinem1,DEMETGÜL Cahit2

Affiliation:

1. HATAY MUSTAFA KEMAL ÜNİVERSİTESİ, FEN-EDEBİYAT FAKÜLTESİ, KİMYA BÖLÜMÜ

2. HATAY MUSTAFA KEMAL ÜNİVERSİTESİ, FEN-EDEBİYAT FAKÜLTESİ, KİMYA BÖLÜMÜ, ANORGANİK KİMYA ANABİLİM DALI

Abstract

In this study, firstly, monoimine compound (H3A) was synthesized from the condensation of 2-aminobenzylamine and 1’-hydroxy-2-acetonaphthone which is a ketone derivative. Asymmetric Schiff base (H2L) was synthesized as a result of the condensation of the obtained H3A and 5-bromosalicylaldehyde. After that, the synthesis and characterization of the Cu(II), Ni(II), Co(II) and Fe(III) complexes of the synthesized H2L compound were carried out. The proposed structures of Schiff bases and its metal complexes were elucidated using analytical and spectroscopic (UV-Vis, FT-IR, elemental, 13C and 1H NMR, LC-MS, ICP-AES, magnetic susceptibility, molar conductivity, and TG-DTA) methods.

Publisher

Igdir University

Subject

General Medicine

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