Economic Evaluation of the Industrial Photosynthesis of Rose Oxide via Lamp or Solar Operated Photooxidation of Citronellol

Author:

Monnerie Nathalie1,Ortner Ju¨rgen1

Affiliation:

1. Deutsches Zentrum fu¨r Luft- und Raumfahrt e.V., Solare Energietechnik; D-51170 Ko¨ln, Germany

Abstract

An economic evaluation regarding the industrial photosynthesis of fine chemical rose oxide using solar light is given and compared to conventional lamps as light source. A plant reaching a capacity of 100 t/a was designed containing app. 1,900 m2 of parabolic troughs, 1,500 m2 of flatbed reactors or 32 high-pressure mercury lamps doped with Thallium iodide (TlI) as a photounit. The investment and production costs were compared and graded. We reached the conclusion that solar application is more profitable than the lamp driven one.

Publisher

ASME International

Subject

Energy Engineering and Power Technology,Renewable Energy, Sustainability and the Environment

Reference12 articles.

1. Sattler, C., Mu¨ller, F.-J., Riffelmann, K.-J., Ortner, J., Funken, K.-H., 1999, “Economic Evaluation and Comparison of the Industrial Photosynthesis of ε-Caprolactam via Solar or Lamp Operated Photooximation of Cyclohexane,” Proc. of Renewable and Advanced Energy Systems for 21st Century, April, Maui, HI, US RAES99-7692.

2. Funken, K.-H., Mu¨ller, F.-J., Ortner, J., Riffelmann, K.-J., and Sattler, C., 1999, “Solar Collectors versus Lamps—A Comparison of the Energy Demand of Industrial Photochemical Process as Exemplified by the Production of ε-Caprolactam,” Energy (Oxford), 24, pp. 681–687.

3. Esser, P., Pohlmann, B., and Scharf, H.-D., 1994, “The PhotochemicalSynthesis of Fine Chemicals with Sunlight,” Angew. Chem. Int. Ed. Engl., 33, pp. 2009–2023.

4. Gollnik, K. , 1982, “Photooxygenation and its Application in Industry,” Chim. Industr., 64, pp. 156–166.

5. Ihr Nachbar, N. N., 2000, Zeitung fu¨r die Nachbarn von Dragoco und Haarmann & Reimer, 1.

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