Surface functionalization of magnetite nanoparticles for remediation enhancement of phenol from aqueous solutions

Author:

Elan Solan Tanusha Devi1,Mahmad Rozi Siti Khalijah2,Md Saleh Noorashikin1,Mohamad Sharifah3,Ishak Ahmad Razali4,Rahim Nurul Yani5,Elan Solan Monisha Devi2

Affiliation:

1. Universiti Kebangsaan Malaysia

2. Universiti Malaysia Perlis

3. University of Malaya

4. Universiti Teknologi MARA

5. Universiti Sains Malaysia

Abstract

Phenol is a toxic pollutant generated by industries. It can diminish the supply of clean water and is hazardous to human health. Hence, an effective abatement method is important to remove phenol from water sources. The following amine-functionalized magnetite nanoparticles, ethylenediamine (EDA), diethylenetriamine (DETA), triethylenetetramine (TETA), tetraethylenepentamine (TEPA), and polyethylenehexamine (PEHA), were used to study the adsorption performances of phenol from the prepared samples. The morphological study revealed long rod shapes with rough and sharp edges, while the elemental analysis presented the addition of two elements, C and N atoms. In addition, the TETA@MNP possessed weaker magnetism compared to MNPs, showing that the surface functionalization of MNPs was successful. TETA@MNP showed the highest percentage for phenol removal compared to others. The TETA@MNP achieved a removal efficiency of 99.2% at optimum conditions of 60 mg dosage, contact time of 25 min, and pH of 7. TETA@MNP obeyed the pseudo-second-order kinetic model and the Freundlich isotherm model, with coefficients of determination (R2) of 0.9765 and 0.9682, respectively. The reusability study has demonstrated that TETA@MNP can be reused approximately 6 times with extremely minor loss. Therefore, TETA@MNP is a good adsorbent for the adsorption of phenol from prepared sample solutions.

Publisher

BioResources

Subject

Waste Management and Disposal,Bioengineering,Environmental Engineering

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3