Abstract
Objectives:This study aims to contribute to establishing the regional effective management of fine particulate matter by evaluating the chemical characteristics and contribution of fine particulate matter, and the accuracy of predictive model of fine particulate matter through the measurement of water-soluble inorganic ions (WSIIs) and electrical conductivity for fine particulate matter generated in Pohang.Methods:PM<sub>10</sub> and PM<sub>2.5</sub> samples were simultaneously collected using a low volume air sampler from April to November 2022. For sample analysis, cations of Ca<sup>2+</sup>, Mg<sup>2+</sup>, K<sup>+</sup>, NH<sub>4</sub><sup>+</sup>, Na<sup>+</sup> and anions of Cl<sup>-</sup>, NO<sub>3</sub><sup>-</sup>, SO<sub>4</sub><sup>2-</sup>, and electrical conductivity were measured after pretreatment by ultrasonic extraction. Results and Discussion:The average concentrations of WSIIs for PM<sub>10</sub> and PM<sub>2.5</sub> in Pohang were 12.1μg/m<sup>3</sup> and 8.5μg/m<sup>3</sup>, respectively, accounting for 35.5% and 50.0% of each fine particulate matter. The sum of NH<sub>4</sub><sup>+</sup>, NO<sub>3</sub><sup>-</sup>, SO<sub>4</sub><sup>2-</sup> concentration was found to account for the majority of 71% and 78% of WSIIs in PM<sub>10</sub> and PM<sub>2.5</sub>, respectively. The PM<sub>2.5</sub>/PM<sub>10</sub> ratios for NH<sub>4</sub><sup>+</sup>, K<sup>+</sup>, and SO<sub>4</sub><sup>2-</sup> were 95%, 89%, and 81%, respectively, mostly present in PM<sub>2.5</sub>. The average ratio of PM<sub>2.5</sub>/PM<sub>10</sub> for NO<sub>3</sub><sup>-</sup> was 54%, but it rose sharply to 79% in November when the temperature was low, indicating an increase in contribution to the generation of PM<sub>2.5</sub> in winter. During the sampling period excluding April and July, the ion balance for cations and anions was relatively good at a 1:1 ratio and showed chemical properties of fine particulate matter close to neutral. A regression model was evaluated for the measured electrical conductivity of WSIIs and the concentration of fine particulate matter. The MAE and RMSE values for PM<sub>2.5</sub> were 1.8μg/m<sup>3</sup> and 2.4μg/m<sup>3</sup>, respectively, which were lower than PM<sub>10</sub> (MAE 7.5 μg/m<sup>3</sup>, RMSE 10.3μg/m<sup>3</sup>), indicating high precision and accuracy. Conclusion:This study confirmed the origin of fine particulate matter generated in Pohang through WSIIs analysis, and suggested that the measured electrical conductivity of WSIIs could be used as a key parameter for measuring the concentration of fine particulate matter.
Funder
Ministry of Environment
National Institute of Environmental Research
Gyeongsangbuk-do
Publisher
Korean Society of Environmental Engineering