Effect of BaTiO3 Doping on the Vibrational Properties of PAni

Author:

Gautam Ratindra1,Nautiyal Vivek Kumar2,Singh Santosh Kumar3,Koranga Bipin Singh,Rawat Seema4

Affiliation:

1. Department of Applied Science, Institute of Engineering and Technology, Dr. Ram Manohar Lohia Awadh University, Ayodhya-224001, U.P., India.

2. Department of Physics, Babasaheb Bhimrao Ambedkar University, Lucknow-226025, U.P, India.

3. Department of Applied Sciences and Humanities, Institute of Engineering and Technology, Lucknow-226021, U.P., India.

4. Department of Physics, Zakir Husain Delhi College, University of Delhi, Delhi-110002, India.

Abstract

Due to the advantages of material abundance and synthetic simplicity, polyaniline can be used as a high-capacity cathode material. However, its practical application in batteries has been hindered by poor electrochemical utilization and cycling instability. This paper reports the enhancement in the conductivity of the polymer (PAni) using the oxidation polymerization method. After successfully synthesis of PAni the vibrational properties have been analyzed by using FTIR. From experimental data, it has been observed that after doping of BaTiO3 the carriers along the surface enhanced which increases vibration along with the fingerprint reason. The polymers showed less electrical conductivity than polyaniline. Unlike polyaniline, the presence of the nitro group caused higher frequency dependence of electrical conductivity. The FTIR bands at 1492, 1291 and 1147 cm−1 are corresponding to the polyaniline salt.

Publisher

Ram Arti Publishers

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