Comparison of high-pressure discharges in mercury and the halides of aluminium, tin and lead

Author:

Chalmers A.G.1,Wharmby D.O.1,Whittaker F.L.1

Affiliation:

1. Thorn Lighting, Research and Engineering Laboratories, Leicester

Abstract

In a search for an efficient metal halide lamp with a continuous spectrum and only one metallic constituent other than mercury, the spectra, luminous efficacies and colour rendering indices of discharges containing the halides of aluminium, tin and lead have been investigated. The luminous efficacies have maxima which depend on the dosing densities of mercury and metal halide. The highest observed luminous efficacies at 400-500 W were about 109 lm/W for AlCl3, 90 lm/W for SnCl2 and 90 lm/W for PbCl 2. Low colour temperatures are obtained at the expense of luminous efficacy and constancy of colour. Arc stability, electrode erosion and reactions with the silica arc tube present problems in making a practical lamp. An alkali halide additive improves the discharges and can provide a high luminous efficacy at a relatively low colour temperature.

Publisher

SAGE Publications

Subject

Electrical and Electronic Engineering,Atomic and Molecular Physics, and Optics

Reference17 articles.

Cited by 5 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Novel molecular discharge light sources;Journal of Physics D: Applied Physics;2011-05-13

2. Molecular structure and vibrational frequencies of lead and tin dihalides: a SCF study;Journal of Molecular Structure: THEOCHEM;1989-06

3. Molecular Composition and Thermochemistry of Tin(II), Lead(II), and Scandium(III) Iodide Vapours;Berichte der Bunsengesellschaft für physikalische Chemie;1985-12

4. Gaseous Chloride Complexes Containing Halogen Bridges;Advances in Inorganic Chemistry;1983

5. A metal halide lamp with ultra-high-color rendering property;Journal of Light & Visual Environment;1977

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