Autoxidation of Spin Finishes

Author:

Fok Wing Y.1,Hild Debra N.1,Petrick Lauren M.1,Obendorf S. Kay2

Affiliation:

1. Department of Textiles and Apparel, Cornell University, Ithaca, New York 14853-4401, U.S.A.

2. Department of Textiles and Apparel, Cornell University, Ithaca, New York 14853-4401, U.S.A.,

Abstract

Spin finishes, including lubricants, emulsifiers, antistatic agents, and wetting agents are used to facilitate the manufacturing and processing of textiles. Autoxidation of ten spin finish components was studied by subjecting them to air and heat over time. Chemical changes were observed visually and evaluated using UV/Vis spectroscopy, viscosity measurements, and Fourier Transform infrared (FTIR) spectroscopy. Yellowing occurred for HCO-16, TMP, wetting agent, coconut oil ethoxylate, and coconut oil. Changes in solubility were observed for wetting agent. Significant changes in viscosity were measured for CO-16, HCO-25, anti-static agent, and wetting agent. Finally, changes in FTIR spectral ratios were observed for CO-25, HCO-16, CO-16, and antistatic agent. Chemical changes observed were consistent with autoxidation of spin finish components.

Publisher

SAGE Publications

Subject

Polymers and Plastics,Chemical Engineering (miscellaneous)

Reference8 articles.

1. Gohl, E. P. G. , and Vilensky, L. D. “Textile Science, an Explanation of Fiber Properties,” 2nd edn, Longman Chesire, Melbourne , 1983, pp. 48-48, 82-82, 87-87, 110-110.

2. Aging of oily soils on textile materials: A literature review

3. Aging of oily soils on textiles. Chemical changes upon oxidation and interaction with textile fibers

4. Mapping of Spin Finish Oils on Nylon 66 Fibers

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