This is the first of our papers on quasi-split affine quantum symmetric pairs
(
U
~
(
g
^
)
,
U
~
ı
)
\big (\widetilde {\mathbf U}(\widehat {\mathfrak g}), \widetilde {{\mathbf U}}^\imath \big )
, focusing on the real rank one case, i.e.,
g
=
s
l
3
\mathfrak g = \mathfrak {sl}_3
equipped with a diagram involution. We construct explicitly a relative braid group action of type
A
2
(
2
)
A_2^{(2)}
on the affine
ı
\imath
quantum group
U
~
ı
\widetilde {{\mathbf U}}^\imath
. Real and imaginary root vectors for
U
~
ı
\widetilde {{\mathbf U}}^\imath
are constructed, and a Drinfeld type presentation of
U
~
ı
\widetilde {{\mathbf U}}^\imath
is then established. This provides a new basic ingredient for the Drinfeld type presentation of higher rank quasi-split affine
ı
\imath
quantum groups in the sequels.