Metal complex catalysis in the chemistry of lower diamondoids

Abstract

The review presents the first survey of published data on the use of compounds, complexes and nanoparticles of transition metals (Fe, Co, Ni, Mn, V, Mo, Cu, Pd, Pt, Rh, Ru, Os, Au, Re and Th) in the catalytic transformations of lower diamondoids — adamantane, diamantane and their derivatives. Catalytic halogenation, oxidation, alkylation and cross-coupling reactions are considered, and the formation pathways of C–N, C–S and C–Se bonds in the series of adamantanoids are discussed. Reaction conditions, appropriate catalytic systems and the structures of products are presented. The bibliography includes 242 references.