Dimeric 1:2 adduct of β,β′-bis(diphenylphosphino)porphyrin with silver(I) chloride-Reference-Cited by-同舟云学术

Dimeric 1:2 adduct of β,β′-bis(diphenylphosphino)porphyrin with silver(I) chloride

Published:2015-01 Issue:01-03 Volume:19 Page:171-174
ISSN:1088-4246
Container-title:Journal of Porphyrins and Phthalocyanines
language:en
Short-container-title:J. Porphyrins Phthalocyanines

Author:

Fujimoto Keisuke¹,Yorimitsu Hideki¹²,Osuka Atsuhiro¹

Affiliation:

1. Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan

2. ACT-C, Japan Science and Technology Agency, Japan

Abstract

A 2,18-bis(diphenylphosphino)porphyrin ligand undergoes complexation with silver(I) chloride to afford a stable phosphine-silver complex. X-ray crystallographic analysis of the complex revealed a dimeric structure of a 1:2 adduct of the diphosphine and silver(I) chloride, where each phosphorus atom coordinates a silver atom. The four AgCl units construct a distorted cubic cluster with small metallophilic interaction. Variable temperature 31 P NMR study exhibited a slow ligand exchange process between 107 Ag and 109 Ag at high temperature.

Publisher

World Scientific Pub Co Pte Lt

Subject

General Chemistry

Link

https://www.worldscientific.com/doi/pdf/10.1142/S1088424615500078

Reference6 articles.

1. A Comparison of Structure and Stability between the Group 11 Halide Tetramers M4X4 (M = Cu, Ag, or Au; X = F, Cl, Br, or I) and the Group 11 Chloride and Bromide Phosphanes (XMPH3)4

2. Cuprophilic Interactions in Luminescent Copper(I) Clusters with Bridging Bis(dicyclohexylphosphino)methane and Iodide Ligands: Spectroscopic and Structural Investigations

3. Four-Coordinate Gold(I), Silver(I), and Copper(I) Complexes with a Large-Span Chiral Ditertiary Phosphine Ligand

4. A One-Pot Diastereoselective Self Assembly of C-Stereogenic Copper(I) Diphosphine Clusters

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