Crown-interlocked lanthanide diphthalocyaninates with switchable panchromatic absorption-Reference-Cited by-同舟云学术

Crown-interlocked lanthanide diphthalocyaninates with switchable panchromatic absorption

Published:2017-04 Issue:04-06 Volume:21 Page:406-415
ISSN:1088-4246
Container-title:Journal of Porphyrins and Phthalocyanines
language:en
Short-container-title:J. Porphyrins Phthalocyanines

Author:

Birin Kirill P.¹,Poddubnaya Anna I.¹²,Isanbaeva Elena V.¹,Gorbunova Yulia G.¹³,Tsivadze Aslan Yu.¹³

Affiliation:

1. A.N. Frumkin Institute of Physical Chemistry and Electrochemistry RAS, 119071, Leninsky pr. 31, Building 4, Moscow, Russia

2. D.I. Mendeleev University of Chemical Technology of Russia, 125047, Miusskaya sq., 9, Moscow, Russia

3. N.S. Kurnakov Institute of General and Inorganic Chemistry RAS, 119991, Leninsky pr. 31, Moscow, Russia

Abstract

New class of clamshell-type lanthanide (Ce(IV), La(III) and Eu(III)) diphthalocyaninates bearing 24-crown-8 linking fragment are synthesized and characterized by means of NMR, UV-vis spectroscopies and MALDI-TOF mass spectrometry. A strong solvatochromism of the complexes, allowing switching the wide-range panchromatic absorption in polar solvents, is demonstrated by means of UV-vis and NMR spectroscopies and attributed to solvent-induced changing of sandwich conformations. The photodegradation of the obtained complexes was also investigated.

Publisher

World Scientific Pub Co Pte Lt

Subject

General Chemistry

Link

https://www.worldscientific.com/doi/pdf/10.1142/S1088424617500353

Reference43 articles.

1. Historic overview and new developments in synthetic methods for preparation of the rare-earth tetrapyrrolic complexes

2. Practical Applications of Phthalocyanines – from Dyes and Pigments to Materials for Optical, Electronic and Photo-electronic Devices

3. A Decade Journey in the Chemistry of Sandwich-Type Tetrapyrrolato−Rare Earth Complexes

4. Molecules for Charge-Based Information Storage

5. An analysis of paramagnetic shifts in proton NMR spectra of non-radical lanthanide(III)-phthalocyanine sandwich complexes

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