PHOTOINDUCED BENDING UPON PULSED IRRADIATION IN AZOBENZENE-CONTAINING CROSSLINKED LIQUID-CRYSTALLINE POLYMERS

Author:

SHIMAMURA AKI1,PRIIMAGI ARRI12,MAMIYA JUN-ICHI1,KINOSHITA MOTOI1,IKEDA TOMIKI1,SHISHIDO ATSUSHI1

Affiliation:

1. Chemical Resources Laboratory, Tokyo Institute of Technology, R1-12, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan

2. Department of Applied Physics, Aalto University, P. O. Box 13500, FI-00076 Aalto, Finland

Abstract

We have investigated the photoresponsive behavior of homogeneously aligned low-azobenzene-concentration crosslinked liquid-crystalline polymers. We compared the thermal contraction and photocontraction of the films, and show that upon UV irradiation, they bend efficiently towards the actinic light source. The photoinduced bending is studied both under continuous-wave irradiation and irradiation with nanosecond pulses. Pulsed irradiation revealed that the photomechanical response can take place within sub-millisecond time scale, and that even a single laser pulse can cause the sample to bend.

Publisher

World Scientific Pub Co Pte Lt

Subject

Physics and Astronomy (miscellaneous),Atomic and Molecular Physics, and Optics,Electronic, Optical and Magnetic Materials

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