New developments in chemistry of organometallic porphyrins and their analogs

Author:

Vecchi Andrea1,Galloni Pierluca1,Floris Barbara1,Nemykin Victor N.2

Affiliation:

1. Dipartimento di Scienze e Tecnologie Chimiche, Università di Roma "Tor Vergata", Via della Ricerca Scientifica, 00133 Rome, Italy

2. Department of Chemistry & Biochemistry, 1039 University Drive, University of Minnesota Duluth, Duluth, MN 55812, USA

Abstract

In this mini-review, new developments in chemistry of organometallic porphyrins and their analogs reported between 2007 and mid 2012 have been discussed. Synthetic strategies for preparation, as well as properties of metallocenyl-type compounds in which organometallic substituents connected to the porphyrinoid via (i) axial coordination; (ii) covalent bond to meso- or β-pyrrolic position; or (iii) β,β′-fused into the aromatic system as well as porphyrinoids with organometallic fragments σ-bonded in η1-fashion were overviewed.

Publisher

World Scientific Pub Co Pte Lt

Subject

General Chemistry

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