Equations of state for fluids based on hard sphere repulsion

Abstract

As is well-known, the structures and thermodynamic properties of fluids are determined by the complex interactions, i.e., the repulsive one and the attractive one, among particles. The simplest equation-of-state (EOS) model maybe the one of hard sphere repulsion plus or multiplying some attraction. Followed by the rapid promotion of the accuracy of hard sphere EOS in the past dozens of years, one question rises as whether more accurate hard sphere repulsion derives better prediction of the structures and properties of fluids with a special attraction. In this work, we used two repulsions with clearly different accuracy and some attractions to construct series equations of state (EOSs) for real fluids, and then we discussed the saturated properties at liquid–gas equilibrium. We found that the answer to the question aforementioned is not definitely standing.