Facile Method of Halogen Exchange between Au(Cl)(L) and MeC(O)X (L = PPh3 and IPr; X = Br and I) via σ-Bond Metathesis Supported by DFT Calculation
Author:
Affiliation:
1. Department of Applied Chemistry, Graduate School of Engineering, Osaka University
2. Institute for Molecular Science
3. ESICB, Kyoto University
Publisher
The Chemical Society of Japan
Subject
General Chemistry
Link
http://www.journal.csj.jp/doi/pdf/10.1246/cl.130335
Reference13 articles.
1. σ-Bond Metathesis between M–X and RC(O)X′ (M = Pt, Pd; X, X′ = Cl, Br, I): Facile Determination of the Relative ΔG Values of the Oxidative Additions of RC(O)X to an M(0) Complex, Evidence by Density Functional Theory Calculations, and Synthetic Applications
2. Gold(I) complexes of unidentate and bidentate phosphorus-, arsenic-, antimony-, and sulphur-donor ligands
3. Can the solid state structures of the dihalogen adducts R3EX2(E = P, As; R = alkyl, aryl; X = Br, I) with the molecular spoke geometry be considered good mimics of the gold(i) systems [(R3E)AuX] (E = As, P; R = alkyl, aryl; X = Cl, Br, I)?
4. Governing the oxidative addition of iodine to gold(i) complexes by ligand tuning
5. Gold(0) Nanoparticles for Selective Catalytic Diboration
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1. Aurophilicity and Photoluminescence of (6‐Diphenylpnicogenoacenaphth‐5‐yl)gold Compounds;European Journal of Inorganic Chemistry;2019-01-17
2. The non-isomorphous crystal structures of NHC—Au—Cl and NHC—Au—Br (NHC is 1,3-dibenzyl-4,5-diphenylimidazol-2-ylidene);Acta Crystallographica Section C Structural Chemistry;2016-10-05
3. Halogen exchange by reaction of CpRu(Cl)(PPh3)2 with MeC(O)X (X = Br, I) and its mechanistic study;Journal of Organometallic Chemistry;2014-10
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