Chemistry of Phosphorus Ylides. Part 27. Metal Complexes of 4-hydroxyquinaldine, its Mannich Base and Phosphonium Ylide-Reference-Cited by-同舟云学术

Chemistry of Phosphorus Ylides. Part 27. Metal Complexes of 4-hydroxyquinaldine, its Mannich Base and Phosphonium Ylide

Published:2009-05 Issue:5 Volume:2009 Page:277-282
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Soliman Fouad¹,Abd-Ellah Ibrahim²,Maigali Soher¹,Abd-El-Naim Gamal¹

Affiliation:

1. Department of Organometallic and Organometalloid Chemistry, National Research Centre, Dokki, Cairo, Egypt

2. Department of Inorganic Chemistry, Faculty of Science, Al-Azhar University, Egypt

Abstract

The reaction of Hg2+,Cd2+,Co2+, and Ni2+ ions with 1 mol of the ligands 2-methylquinoline-4-ol,3[(diethylamino)methyl]-2-methylquinoline-4-ol, and methyl-3-(4-hyrdoxy-2-methylquinoline-3-yl)-2-(triphenylphosphoranylidene)propanoate, has been investigated to give the corresponding 1:1 metal:ligand complexes. Reaction of 2 mol of the ligand gave the corresponding 1:2 metal:ligand complexes. The coordination takes place only through the quinoline nitrogen atom. The spectroscopic and the physicochemical data of the new metal complexes are discussed.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823409X440841

Reference26 articles.

1. Chemistry of phosphorus ylides. Part 24 [1]. A route for the synthesis of oxazine derivatives via the reaction of phosphacumulenes and phosphallene with di- and tri-ketone monoximes

2. Synthesis and antimicrobial activity of meso-substituted polymethine cyanine dyes

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