Synthesis of perialkynylated tetrapyrazinoporphyrazines and its Optical Properties-Reference-Cited by-同舟云学术

Synthesis of perialkynylated tetrapyrazinoporphyrazines and its Optical Properties

Published:2009-05 Issue:5 Volume:2009 Page:312-316
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Jang Chun Keun¹,Jaung Jae Yun¹

Affiliation:

1. Department of Fiber and Polymer Engineering, Hanyang University 17 Haengdang-dong, Seongdong-gu, Seoul, 133791, Korea

Abstract

Some phthalocyanines soluble in organic solvents have been developed by peripheral introduction of substituent groups. We report a new method for preparation of the polyphenyl-substituted dicyanopyrazines based on the [2 + 4] Diels-Alder cycloaddition of the tetraphenylcyclopentadienone to an ethynyl compound. The synthesised tetrapyrazinoporphyrazinato metal complexes were characterised by UV-visible spectroscopy, MALDI-TOF-Ms (matrix-assisted laser desorption ionisation time-of-flight mass) spectroscopy, and 1H NMR spectroscopy.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823409X449473

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