New Scorpionate Oxovanadium Complexes: Syntheses and Crystal Structures of a Series of Vanadium (IV) Complexes with Mixed Ligands of Polypyrazolylborates and Substituted Acetylacetonates

Author:

Xing Yong Heng1,Aoki Katsuyuki2,Sun Zheng3,Ge Mao Fa3,Niu Shuyun1

Affiliation:

1. College of Chemistry and Chemical Engineering, Liaoning Normal University, Huanghe Road 850#, Dalian, 116029, China

2. Department of Materials Science, Toyohashi University of Technology, 441-8580, Japan

3. Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100080, China

Abstract

The reaction of [VO(R1-acac)2] (R1 = Me or Et; acac = acetylacetonate) with Na[HB(pz)3] (pz = pyrazole) or Na[HB(3,5-Me2pz)3] in MeOH gave a series of new oxovanadium (IV) complexes: [VO{HB(pz)3}(Me-acac)] (1), [VO{HB(3,5-Me2pz)3}(Me-acac)] (2), [VO{HB(pz)3}(Et-acac)] (3) and [VO{HB(3,5-Me2pz)3}(Et-acac)] (4), respectively. All complexes have similar distorted octahedral coordination about vanadium, [VO(N3O2)], in which the basal plane is defined by the N4, N6 atoms from the tridentate ligand and the O2, O3 atoms from the R1-acac ligand. However, the dihedral angles between the plane formed by O2, V and O3, and the plane of the pentane-2, 4-dionato ligand (O2, C1, C2, C3 and O3) are variously different; 3.59° for 1, 74.54° for 2, 0.92° for 3, and 29.50° for 4, respectively. In addition, ab initio calculations on 1, 2, 3 and 4 have given the energies and characters of the selected MOs, the atomic net charge and the NBO bond order. The order of stability of the complexes is 1 ≅ 2 ≅ 4 > 3.

Publisher

SAGE Publications

Subject

General Chemistry

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