The Effective Preparation of Secondary Amines Bearing a Vinylsilane Functionality via the reaction of Primary Amines with α-chlorine-substituted Allylsilanes Catalysed by CuCl-Reference-Cited by-同舟云学术

The Effective Preparation of Secondary Amines Bearing a Vinylsilane Functionality via the reaction of Primary Amines with α-chlorine-substituted Allylsilanes Catalysed by CuCl

Published:2007-08 Issue:8 Volume:2007 Page:464-467
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Kozuka Makoto¹,Mitani Michiharu¹

Affiliation:

1. Department of Chemistry and Material Engineering, Faculty of Engineering, Shinshu University, Wakasato 4-17-1, Nagano 380-8551, Japan

Abstract

The reaction of α-chlorine-substituted allylsilanes with primary amines was promoted by CuCl to result in the selective formation of secondary amines bearing the vinylsilane functionality by a probable SN2′-allylation keeping the silyl group intact.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823407X237795

Reference11 articles.

1. Preparation of (+)-N-methyl-1-(1-naphthyl)ethylamine and the determination of its optical purity by nuclear magnetic resonance

2. SOME NUCLEUS ALKYL DERIVATIVES OF PHENETHYLAMINE* †

3. Palladium(o)-catalyzed hydroxylamination of allyl esters

4. SYNTHETIC APPLICATION OF AMINOSILANES SELECTIVE FORMATION OF SECONDARY AMINES WITH AMINOSILANES

5. Copper(I) Chloride-Catalyzed Three-Component Coupling Reaction of Primary Amines with Electrophiles and α-Halogen-Substituted Allylsilanes to Form Unsymmetrical Tertiary Amines

Cited by 1 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. ChemInform Abstract: The Effective Preparation of Secondary Amines Bearing a Vinylsilane Functionality via the Reaction of Primary Amines with α-Chlorine-Substituted Allylsilanes Catalyzed by CuCl.;ChemInform;2008-02-19