Diene-yne cyclisation reactions of 1-ethynyl-2-vinyl-3,4-dihydronaphthalenes and 1-ethynyl-2-vinylnaphthalenes-Reference-Cited by-同舟云学术

Diene-yne cyclisation reactions of 1-ethynyl-2-vinyl-3,4-dihydronaphthalenes and 1-ethynyl-2-vinylnaphthalenes

Published:2008-12 Issue:12 Volume:2008 Page:669-678
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Watanabe Masataka¹,Shiine Kodai¹,Ideta Keiko²,Matsumoto Taisuke²,Thiemann Thies¹

Affiliation:

1. Interdisciplinary Graduate School of Engineering, Kyushu University, 6-7, Kasuga-koh-en, Kasuga-shi, Fukuoka 816-8580, Japan

2. Institute of Materials Chemistry and Engineering, Kyushu University, 6-7, Kasuga-koh-en, Kasuga-shi, Fukuoka 816-8580, Japan

Abstract

The reaction of 1-ethynyl-2-vinyl-3,4-dihydronaphthalenes and 1-ethynyl-2-vinylnaphthalenes over RuCl2(p-cymene) PPh3 leads to 9,10-dihydrophenanthrenes and phenanthrenes in those cases where the ethynyl group in the substrates carries a terminal proton. When 1-phenylethynyl-2-vinyl-3,4-dihydronaphthalenes or 1-phenylethynyl-2-vinylnaphthalenes are reacted over Pt(PPh3)4, 1-methylene-1H-benz[e]-4,5-dihydroindenes and 1-methylene-1H-benz[e]indenes are formed.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823408X375214

Reference48 articles.

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2. Chelation-Controlled Bergman Cyclization: Synthesis and Reactivity of Enediynyl Ligands

3. Benzol durch Pyrolyse voncis- undtrans- 1,3-Hexadien-5-in

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