Affiliation:
1. College of Chemical Engineering, Shandong University of Technology, Zibo 255049, P.R. China
Abstract
Three chiral manganese(III) Schiff-base complexes [Mn(R,R-Salcy)(CH3OH)(N3)], [Mn(S,S-Salcy)(DMF)(N3)] (both monomers by X-structure determination) and the trinuclear complex (X-ray structure) {[Mn(R,R-Salcy)(H2O)]2[μ-Ni(CN)4]}·3CH3OH·H2O [Salcy = N,N′-(1,2-cyclohexanediylethylene)bis(salicylideneiminato)dianion)] have been synthesised. The trimeric complex shows weak antiferromagnetic interactions between the adjacent Mn(III) ions.
Cited by
4 articles.
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1. Introduction to tetracyanometalate bridged transition metal-salen complexes: Synthesis, structure and properties;Polyhedron;2022-09
2. Synthetic strategy and structures of [Cr(CN)6]3−, [Mo(CN)8]3− and [W(CN)8]3− bridged di- and poly-nuclear transition metal-salen complexes: A review;Results in Chemistry;2022-01
3. The crystal structure of (azido)-κ1
N-6,6′-((cyclohexane-1,2-diylbis(azanylylidene)) bis(methanylylidene))bis(3-bromophenolato-
κ
4
N,N,O,O)-(methanol)-manganese(III)–methanol(1/1), C
22
H
26
Br
2
MnN
5
O
4;Zeitschrift für Kristallographie - New Crystal Structures;2021-03-08
4. Synthesis, Crystal Structure and Magnetic Properties of [Mn((1R
, 2R
)-Salcy)N3
/NCS] Complexes: Solvent Dependent Crystallization of Monomers, Chains and Dimers.;ChemistrySelect;2017-09-11