Carbolithiation of Styrenes with N-tert-butyl aldimines-Reference-Cited by-同舟云学术

Carbolithiation of Styrenes with N-tert-butyl aldimines

Published:2012-12 Issue:12 Volume:36 Page:732-735
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Liu Jie¹,Dang Hai-Shan¹

Affiliation:

1. Fragrance Science & Technology, Givaudan Fragrances (Shanghai) Ltd, 298 Li Shi Zhen Road, Shanghai 201203, P. R. China

Abstract

The addition of aldimine anions to styrene occurs upon the treatment of N-tert-butyl aldimine with LDA followed by the addition of styrene to give the corresponding aldehyde after hydrolysis. Cyclohexenyl amines are generated when the reactions are performed with unsaturated aldimines. This approach affords 4-phenyl substituted butanals and cyclohexenyl amines in a simple and inexpensive way.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/174751912X13528268645571

Reference34 articles.

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1. Highly regioselective synthesis of branched saturated aldehydes by tandem hydroformylation/isomerization/hydrogenation of 1-arylbutadienes;Monatshefte für Chemie - Chemical Monthly;2024-06-13

2. ChemInform Abstract: Carbolithiation of Styrenes with N-tert-Butyl Aldimines.;ChemInform;2013-04-18