A Comprehensive Kinetic Study of the SO2 Removal Reaction by Pure CuO with the Random Pore Model-Reference-Cited by-同舟云学术

A Comprehensive Kinetic Study of the SO2 Removal Reaction by Pure CuO with the Random Pore Model

Published:2016-11 Issue:4 Volume:41 Page:385-397
ISSN:1468-6783
Container-title:Progress in Reaction Kinetics and Mechanism
language:en
Short-container-title:Progress in Reaction Kinetics and Mechanism

Author:

Bahrami Reza¹,Ebrahim Habib Ale¹,Halladj Rouein¹,Afshar Ali²

Affiliation:

1. Department of Chemical Engineering, Amirkabir University of Technology, 424 Hafez Ave, Tehran, Iran

2. Iran Polymer and Petrochemical Institute, Faculty of Petrochemicals, PO Box 14965/115, Tehran, Iran

Abstract

An experimental investigation of the SO2 removal reaction by pure CuO was performed by thermogravimetry. In addition, mathematical modelling of this non-catalytic gas-solid reaction was performed using the random pore model. Modelling predictions of CuO conversion-time profiles at various temperatures and SO2 partial pressures compared well with the experimental results. The inherent rate constants and the product layer diffusivities were estimated between 400 and 600 °C.

Publisher

SAGE Publications

Subject

Physical and Theoretical Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/146867816X14716171449503

Reference27 articles.

1. KirkR.E., OthmerD.F., KroschwitzJ.I., and Howe-GrantM. (1991) Encyclopedia of chemical technology, Vol. 12, pp. 318–340. John Wiley and Sons, New York.

2. Recent advances in the science and technology of ultra low sulfur diesel (ULSD) production

3. Promoter effect of vanadia on Co/Mo/Al2O3 catalyst for deep hydrodesulfurization via the hydrogenation reaction pathway

4. NiMo/Al2O3 catalyst containing nano-sized zeolite Y for deep hydrodesulfurization and hydrodenitrogenation of diesel

5. Kirk-Othmer. (1995) Encyclopedia of chemical technology, Vol. 1, pp. 762–767. John Wiley and Sons, New York.

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