Enhanced toluene removal from aqueous solutions using reed straw-derived biochar

Author:

Lv Haorui1,Leng Haihan2,Li Bohan3,Wang Qianyu4,Ma Ximan5,Zhou Runxuan6,Yue Xiaoju78,Wu Guodong79

Affiliation:

1. Beijing No. 57 Middle School , 6 Beifengwo Middle Road, Haidian District, Beijing 100038, China

2. Shenzhen Senior High School , 8 Zetian Road, Futian District, Shenzhen 518057, China

3. Beijing National Day School , 66 Yuquan Road, Haidian District, Beijing 100062, China

4. Beijing Haidian Foreign Language Shiyan School , 20 Xingshikou Road, Haidian District, Beijing 100095, China

5. University of Toronto Scarborough Department of Physical and Environment Science, , 1265 Military Trail, Toronto, ON M1C 1A4, Canada

6. High School Affiliated to Renmin University of China , 37 Zhongguancun Street, Haidian District, Beijing 100080, China

7. Hofmann Institute of Advanced Materials , Shenzhen Polytechnic, Shenzhen 518055, China

8. Tibet University Innovation Laboratory of Materials for Energy and Environment Technologies, Institute of Oxygen Supply and College of Science, , Lhasa 850000, China

9. Xinjiang University School of Future Technology, , Urumqi 830049, China

Abstract

Abstract The escalating threat of pollutants, particularly aromatic hydrocarbons like benzene, toluene, ethylbenzene and xylene (BTEX), in aquatic environments necessitates effective remediation strategies. This study explores the potential of biochar derived from common reed (Phragmites australis) as a sustainable and multifaceted tool for the removal of toluene, a representative BTEX compound, from aqueous solutions. By harnessing reed straw as the precursor material for biochar production, this research showcases an environmentally friendly alternative to conventional disposal methods, such as incineration, offering the dual benefit of pollutant removal and carbon emissions reduction. The influence of pyrolysis temperature on biochar properties and its adsorption efficiency for toluene were rigorously examined, revealing a direct correlation between temperature and biochar’s pollutant sequestration capabilities. Results indicate that higher pyrolysis temperatures led to biochar (RB-750) with superior specific surface area (68.07 m2/g) and enhanced adsorption capabilities, demonstrating its potential as a powerful adsorbent in water treatment. The scanning electron microscope analysis revealed a complex, porous structure rich in active sites, validating the biochar’s suitability for pollutant adsorption. Optimal dosage was determined at 8 g/l, achieving an impressive toluene removal efficiency of 98.1%. Additionally, pH and initial toluene concentration significantly influenced removal efficiency. This study underscores the multifaceted potential of reed straw-derived biochar in combating water pollution while concurrently contributing to carbon emissions reduction through sustainable utilization of abundant wetland resources. Further research should delve into the impact of real-world conditions on its effectiveness, promising innovative solutions for environmental remediation efforts with a reduced carbon footprint.

Publisher

Oxford University Press (OUP)

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