Effective incorporation of Ti atom into TS-1 zeolite assisted with oxalic acid additive-Reference-Cited by-同舟云学术

Effective incorporation of Ti atom into TS-1 zeolite assisted with oxalic acid additive

Published:2024-08-30 Issue:9 Volume:53 Page:
ISSN:0366-7022
Container-title:Chemistry Letters
language:en
Short-container-title:

Author:

Techasarintr Piyapatch¹,Yin Liu¹,Wang Yong¹,Xiao Peipei¹,Bekhti Samya¹,Kondo Junko N¹,Yokoi Toshiyuki¹²

Affiliation:

1. Institute for Innovative Research, Tokyo Institute of Technology , 4259 Nagatsuta, Midori-ku, Yokohama 226-8501 , Japan

2. iPEACE223 Inc. , Konwa Building, 1-12-22 Tsukiji, Chuo-ku, Tokyo 104-0045 , Japan

Abstract

Abstract The effect of introducing oxalic acid into the mother gel of TS-1 zeolite on the crystallization behavior and physiochemical properties was investigated. The addition of oxalic acid with a buffering action significantly accelerated the crystallization process of TS-1 while simultaneously inhibiting the formation of anatase. The resultant TS-1 zeolites displayed enhanced performance in catalyzing the epoxidation of 1-hexene with H2O2 as an oxidant.

Funder

JSPS KAKENHI

Publisher

Oxford University Press (OUP)

Link

https://academic.oup.com/chemlett/advance-article-pdf/doi/10.1093/chemle/upae170/58979342/upae170.pdf

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4. Coke deposition and characterization on titanium silicalite-1 catalyst in cyclohexanone ammoximation