Influence of structural isomers of naphthalene diimides on photophysical and electrochemical properties

Author:

Yamamoto Yusei1,Horioka Ami1,Cui Luxia1,Ishigaki Yusuke2,Hoshino Yu13,Ono Toshikazu13

Affiliation:

1. Department of Applied Chemistry, Graduate School of Engineering, Kyushu University , 744 Motooka, Nishi-ku , Fukuoka 819-0395, Japan

2. Department of Chemistry, Faculty of Science, Hokkaido University , Sapporo 060-0810 , Japan

3. Center for Molecular Systems (CMS), Kyushu University , 744 Motooka, Nishi-ku , Fukuoka 819-0395, Japan

Abstract

Abstract Three structural isomers of naphthalene diimides were synthesized. In all compounds, the electron-withdrawing diimide group exhibits a stable two-step reduction behavior under electrochemical conditions, and it was revealed that their reduction potentials vary significantly depending on the position of the diimide group relative to the naphthalene ring.

Funder

JSPS

Publisher

Oxford University Press (OUP)

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