Shaping of metal–organic framework using chitosan and triphosphate cross-linker

Author:

Witono Aditya Irfan1,Zheng Xin12,Saito Yuki12,Noro Shin-ichiro12

Affiliation:

1. Graduate School of Environmental Science, Hokkaido University , N10W5, Kita-ku, Sapporo 060-0810 , Japan

2. Faculty of Environmental Earth Science, Hokkaido University , N10W5, Kita-ku, Sapporo 060-0810 , Japan

Abstract

Abstract The Zr metal–organic framework (MOF) UiO-66 was shaped into beads using chitosan and P3O105− as a cross-linker. The obtained UiO-66–chitosan beads showed decreases in pore size and Brunauer–Emmett–Teller (BET) surface area but enhanced N2 adsorption energy with retention of Zr-ligand connectivity. This finding will provide an important insight into the practical application of MOFs.

Funder

JST SPRING

Publisher

Oxford University Press (OUP)

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