Photolysis of frozen iodate salts as a source of active iodine in the polar environment

Abstract

Abstract. Reactive halogens play a key role in the oxidation capacity of the polar troposphere. However, sources and mechanisms, particularly those involving active iodine, are still poorly understood. In this paper, the photolysis of an atmospherically relevant frozen iodate salt has been experimentally studied using infrared (IR) spectroscopy. The samples were generated at low temperatures in the presence of different amounts of water. The IR spectra have confirmed that under near-UV/Vis radiation iodate is efficiently photolyzed. The integrated IR absorption coefficient of the iodate anion on the band at 750 cm−1 has been measured to be A = 9.5 × 10−17 cm molec−1. Using this value, a lower limit of the integrated absorption cross section of iodate, in an ammonium frozen salt, has been estimated for the first time at wavelengths relevant for tropospheric studies (σ = 1.1 × 10−20 cm2 nm molec−1 from 300 to 900 nm). According to this, we suggest that the photolysis of iodate in frozen salt can potentially provide a pathway for the release of active iodine to the polar atmosphere.