Abstract
Abstract. Cloud droplet activation of wettable insoluble compounds has been studied theoretically by assuming that droplet growth happens through multilayer adsorption. The idea is to include an adsorption isotherm in Köhler theory instead of the solute term. This makes it possible to describe the equilibrium growth of insoluble particles and to find out their critical saturation ratios. The critical saturation ratios calculated in this way are comparable to those of completely soluble particles at certain ranges of adsorption isotherm parameter values. The results indicate that adsorption could cause wettable insoluble compounds to activate in atmospheric conditions. However, more data on the adsorption parameters for wettable organic substances is needed to confirm this conclusion.
Reference27 articles.
1. Adamson, A W.: An adsorption model for contact angle and spreading, J. Colloid and Interface Sci., 27, 180–187, 1968.
2. Adamson, A W. and Gast, A P.: Physical Chemistry of Surfaces, John Wiley & Sons Inc., 6th edition, 617–618, 1997.
3. Bilde, M. and Svenningsson, B.: CCN activation of slightly soluble organics: the importance of smalla amounts of salt and particle phase, Tellus, 56B, 128–134, 2004.
4. Boyd, G E. and Livingston, H K.: Adsorption and energy change at crystalline solid surfaces, J. Am. Chem. Soc., 64, 2383–2388, 1942.
5. Carrot, P. J M. and Sing, K. S W.: Adsorption of nitrogen and alkanes by non-porous carbons and silicas, Pure Appl. Chem., 61, 1835–1840, 1989.
Cited by
82 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献